[Question from NMRWiki Q&A forum] Correlations across glycosidic bonds
Correlations across glycosidic bonds
I am studying carbohydrates and was wanting to know if it was possible to record correlations through the ether linkage of the glycosidic bond in sugars either from the proton or carbon of one sugar top the adjacent sugar or the protons of a Serine or threonine side chain in a glyco-peptide. Would something like a 13C-HSQC-TOCSY cross the glycosidic bond? if not are there experiments that would?
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