in the answer you read:"The 13C-19F isotope shift can be fairly large, so the satellites wouldn't be symmetric."
13C-19F isotope shift: they mean satellites dues to 13C-19F coupling, right? So if it is so large, they are not symmetric in Hz scale but symmetric in ppm scale? I can't understand this!
I have seen asymmetric small peaks around 19F-spectrum of perfluorohexane. But I guessed they might be due to some other artifacts!
Thanks for the time,Amin
Check if somebody has answered this question on NMRWiki QA forum
Did you find this post helpful? |
Similar Threads
Thread
Thread Starter
Forum
Replies
Last Post
[NMRpipe Yahoo group] Integration of Peaks using NMR Draw
Integration of Peaks using NMR Draw
Hello, Using scripts I have created my .ft2 file to visualize my 1D 13C data in nmrDraw. I would like to integrate the area for the carbonyl's and the spinning
More...
NMRpipe Yahoo group news
News from other NMR forums
0
12-21-2011 04:59 PM
[NMRpipe Yahoo group] Asymmetric peaks
Asymmetric peaks
Dear users, I have a NOESY filtered in F2 but not in F1 so I expect symmetric peaks (not usefuls) and asymmetryc peaks. Does NMRPipe contains a script/command
More...
NMRpipe Yahoo group news
News from other NMR forums
0
07-06-2011 06:21 PM
[Question from NMRWiki Q&A forum] negative NMR peaks
negative NMR peaks
I am very new to NMR and have little experience of it. However I am trying to use it to determine the composition of a mixture. A spectra which I have just obtained contains negative peaks which are giving me incorrect inegrals.
What would cause this? and is there any way to correct it? I can't find much in literature regarding this.
Thanks for your help
Dean
nmrlearner
News from other NMR forums
0
06-21-2011 03:40 PM
[Question from NMRWiki Q&A forum] NMRPipe: re-integrate peaks
NMRPipe: re-integrate peaks
Hello,
I am familiarizing myself with NMRPipe and I have a question similar to the one already asked (http://qa.nmrwiki.org/question/145/what-software-can-copy-peak-assignments-for-2d-t1-and-t2-relaxation-rate-data-analysis). I want to perform assignments in one spectrum and transfer them to another one. I have used ipap.tcl as advised, but the peak heights got also propagated into the new file. Is it possible to re-read the heights from the spectrum for the generated assignment table?
The syntax I used was:ipap.tcl -specName1 assigned.ft -specName2...
[NMR paper] Suppression of diagonal peaks in TROSY-type 1H NMR NOESY spectra of 15N-labeled prote
Suppression of diagonal peaks in TROSY-type 1H NMR NOESY spectra of 15N-labeled proteins.
Related Articles Suppression of diagonal peaks in TROSY-type 1H NMR NOESY spectra of 15N-labeled proteins.
J Magn Reson. 1999 Oct;140(2):499-503
Authors: Meissner A, Sørensen OW
A novel method for suppression of diagonal peaks in the amide region of NOESY NMR spectra of 15N-labeled proteins is presented. The method is particularly useful for larger proteins at high magnetic fields where interference between dipolar and chemical shift anisotropy relaxation...
nmrlearner
Journal club
0
11-18-2010 08:31 PM
[NMR analysis blog] Riding up the peaks …
Riding up the peaks …
… around the Pyrenees. NMR peaks are not the only ones that interest us in Mestrelab, we also love the Cols in the Tour de France, and I have some proof :-) :
http://4.bp.blogspot.com/_-MfflvAgRls/TE68R9s8slI/AAAAAAAAAnE/kcXdrIJZeFo/s400/Tour1.jpg
Quoting a friend of mine: I had never seen the Yellow Jersey before. It is a bit surprising that the competitors would fight so hard for the right to wear it :-)
Even though I’m not a great fan of Lance Armstrong, I reckon he has incredibly popularized cycling in the US. The guy in the photo has been following him...