We present designs for compact, inexpensive and strong dipole permanent magnets aimed primarily at magnetic resonance applications where prepolarization and detection occur at different locations. Low-homogeneity magnets with a 7.5mm bore size and field up to nearly 2T are constructed using low-cost starting materials, standard workshop tools and only few hours of labor - an achievable project for a student or postdoc with spare time. As an application example we show how our magnet was used to polarize the nuclear spins in approximately 1mL of pure [13C]-methanol prior to detection of its high-resolution NMR spectrum at zero field (measurement field below 10-10T), where signals appear at multiples of the carbon-hydrogen spin-spin coupling frequency 1JCH=140.7(1)Hz.
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[NMR paper] Natural abundant (17) O NMR in a 1.5-T Halbach magnet.
Natural abundant (17) O NMR in a 1.5-T Halbach magnet.
Natural abundant (17) O NMR in a 1.5-T Halbach magnet.
Magn Reson Chem. 2015 Jan 16;
Authors: Sørensen MK, Bakharev ON, Jensen O, Nielsen NC
Abstract
We present mobile, low-field (17) O NMR as a means for monitoring oxygen in liquids. Whereas oxygen is one of the most important elements, oxygen NMR is limited by a poor sensitivity related to low natural abundance and gyro-magnetic ratio of the NMR active (17) O isotope. Here, we demonstrate (17) O NMR detection at a...
A cost-effective look at proteins - with a little help from robotics - Cordis News
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A cost-effective look at proteins - with a little help from robotics
Cordis News
Until now, a number of methods have been used to study static protein structures, including X-ray crystallography and nuclear magnetic resonance. However, these methods are of no use for proteins that are on the move; analytical methods, computer ...
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A cost-effective look at proteins - with a little help from...
nmrlearner
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09-14-2013 01:46 AM
[NMR paper] Anisotropy of Rotational Diffusion, Dipole-Dipole Cross-Correlated NMR Relaxation and Angles between Bond Vectors in Proteins.
Anisotropy of Rotational Diffusion, Dipole-Dipole Cross-Correlated NMR Relaxation and Angles between Bond Vectors in Proteins.
Related Articles Anisotropy of Rotational Diffusion, Dipole-Dipole Cross-Correlated NMR Relaxation and Angles between Bond Vectors in Proteins.
Chemphyschem. 2001 Sep 17;2(8-9):539-43
Authors: Deschamps M, Bodenhausen G
Abstract
Cross correlations between the fluctuations of dipolar (13) C(?) -(1) H(?) interactions yield information about the relative orientation of successive (13) C(?) -(1) H(?) bond vectors...
[NMR Sparky Yahoo group] Re: Pseudo 3D T2_relaxation
Re: Pseudo 3D T2_relaxation
Hi Mohammed, I could envision several solutions to your problem. The easiest is simply this: transform your spectra so that each plane corresponds to a single
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nmrlearner
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05-16-2011 08:22 AM
[NMR paper] The electric dipole moment of DNA-binding HU protein calculated by the use of an NMR
The electric dipole moment of DNA-binding HU protein calculated by the use of an NMR database.
Related Articles The electric dipole moment of DNA-binding HU protein calculated by the use of an NMR database.
Biophys Chem. 1999 Aug 30;80(3):153-63
Authors: Takashima S, Yamaoka K
Electric birefringence measurements indicated the presence of a large permanent dipole moment in HU protein-DNA complex. In order to substantiate this observation, numerical computation of the dipole moment of HU protein homodimer was carried out by using NMR protein...
nmrlearner
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11-18-2010 08:31 PM
[NMR paper] Attenuated T2 relaxation by mutual cancellation of dipole-dipole coupling and chemica
Attenuated T2 relaxation by mutual cancellation of dipole-dipole coupling and chemical shift anisotropy indicates an avenue to NMR structures of very large biological macromolecules in solution.
http://www.ncbi.nlm.nih.gov/corehtml/query/egifs/http:--highwire.stanford.edu-icons-externalservices-pubmed-custom-pnas_full_free.gif http://www.ncbi.nlm.nih.gov/corehtml/query/egifs/http:--www.pubmedcentral.nih.gov-corehtml-pmc-pmcgifs-pubmed-pmc.gif Related Articles Attenuated T2 relaxation by mutual cancellation of dipole-dipole coupling and chemical shift anisotropy indicates an...