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Ha, M. and V.K. Michaelis, High-Frequency Dynamic Nuclear Polarization NMR for Solids: Part 1 – An Introduction, in Modern Magnetic Resonance, G.A. Webb, Editor. 2017, Springer International Publishing: Cham. p. 1-24.
Dynamic nuclear polarization (DNP) NMR spectroscopy, a high-polarization method, is rapidly changing the landscape of what is possible in solid-state nuclear magnetic resonance spectroscopy. To date, there have been over 200 publications discussing high-frequency DNP NMR of solids with more than half being released within the past few years. Below we provide for researchers that may be interested in this high-sensitivity technique an introduction to high-frequency DNP NMR spectroscopy, including instrumentation, mechanisms, polarizing agents, and sample preparation. While there are many applications utilizing high-frequency DNP NMR, Part II will deal with recent advances in method development and applications to biomolecular solids and materials science.
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Electron Decoupling with Dynamic Nuclear Polarization in Rotating Solids #DNPNMR
From The DNP-NMR Blog:
Electron Decoupling with Dynamic Nuclear Polarization in Rotating Solids #DNPNMR
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Saliba, E.P., et al., Electron Decoupling with Dynamic Nuclear Polarization in Rotating Solids. J Am Chem Soc, 2017. 139(18): p. 6310-6313.
https://www.ncbi.nlm.nih.gov/pubmed/28429936
nmrlearner
News from NMR blogs
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08-11-2017 08:52 PM
A tailored multi-frequency EPR approach to accurately determine the magnetic resonance parameters of dynamic nuclear polarization agents: application to AMUPol #DNPNMR
From The DNP-NMR Blog:
A tailored multi-frequency EPR approach to accurately determine the magnetic resonance parameters of dynamic nuclear polarization agents: application to AMUPol #DNPNMR
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This is a very nice article illustrating the importance of understanding the EPR parameters of a polarizing agent used in DNP-NMR spectroscopy. Here the 9, 95 and 275 GHz EPR spectroscopy is used to characterize AMUPol and predict its performance in high-field DNP.
nmrlearner
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06-05-2017 03:59 PM
Temperature dependence of cross-effect dynamic nuclear polarization in rotating solids: advantages of elevated temperatures #DNPNMR
From The DNP-NMR Blog:
Temperature dependence of cross-effect dynamic nuclear polarization in rotating solids: advantages of elevated temperatures #DNPNMR
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Geiger, M.A., et al., Temperature dependence of cross-effect dynamic nuclear polarization in rotating solids: advantages of elevated temperatures. Phys. Chem. Chem. Phys., 2016. 18(44): p. 30696-30704.
https://www.ncbi.nlm.nih.gov/pubmed/27791210
nmrlearner
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01-25-2017 11:13 PM
Correction: Theory of solid effect and cross effect dynamic nuclear polarization with half-integer high-spin metal polarizing agents in rotating solids #DNPNMR
From The DNP-NMR Blog:
Correction: Theory of solid effect and cross effect dynamic nuclear polarization with half-integer high-spin metal polarizing agents in rotating solids #DNPNMR
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Corzilius, B., Correction: Theory of solid effect and cross effect dynamic nuclear polarization with half-integer high-spin metal polarizing agents in rotating solids. Phys. Chem. Chem. Phys., 2016. 18(42): p. 29643-29643.
http://dx.doi.org/10.1039/C6CP90249A
nmrlearner
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12-17-2016 07:18 AM
Theory of solid effect and cross effect dynamic nuclear polarization with half-integer high-spin metal polarizing agents in rotating solids #DNPNMR
From The DNP-NMR Blog:
Theory of solid effect and cross effect dynamic nuclear polarization with half-integer high-spin metal polarizing agents in rotating solids #DNPNMR
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Corzilius, B., Theory of solid effect and cross effect dynamic nuclear polarization with half-integer high-spin metal polarizing agents in rotating solids. Phys. Chem. Chem. Phys., 2016. 18(39): p. 27190-27204.
http://dx.doi.org/10.1039/C6CP04621E
nmrlearner
News from NMR blogs
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11-21-2016 11:02 PM
Magic Angle Spinning NMR of Proteins: High-Frequency Dynamic Nuclear Polarization and H Detection
From The DNP-NMR Blog:
Magic Angle Spinning NMR of Proteins: High-Frequency Dynamic Nuclear Polarization and H Detection
Su, Y., L. Andreas, and R.G. Griffin, Magic Angle Spinning NMR of Proteins: High-Frequency Dynamic Nuclear Polarization and H Detection. Annu Rev Biochem, 2015.
http://www.ncbi.nlm.nih.gov/pubmed/25839340
nmrlearner
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04-17-2015 08:49 PM
[NMR paper] Magic Angle Spinning NMR of Proteins: High-Frequency Dynamic Nuclear Polarization and (1)H Detection.
Magic Angle Spinning NMR of Proteins: High-Frequency Dynamic Nuclear Polarization and (1)H Detection.
Magic Angle Spinning NMR of Proteins: High-Frequency Dynamic Nuclear Polarization and (1)H Detection.
Annu Rev Biochem. 2015 Mar 30;
Authors: Su Y, Andreas L, Griffin RG
Abstract
Magic angle spinning (MAS) NMR studies of amyloid and membrane proteins and large macromolecular complexes are an important new approach to structural biology. However, the applicability of these experiments, which are based on (13)C- and...
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Journal club
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04-04-2015 05:31 PM
High Frequency Dynamic Nuclear Polarization
From The DNP-NMR Blog:
High Frequency Dynamic Nuclear Polarization
Ni, Q.Z., et al., High Frequency Dynamic Nuclear Polarization. Acc Chem Res, 2013.
http://www.ncbi.nlm.nih.gov/pubmed/23597038
High-Frequency Dynamic Nuclear Polarization NMR for Solids: Part 1 – An Introduction #DNPNMR
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