This article is already a bit older. However, it nicely illustrates that DNP, specifically ODNP has been around for a while already, and gives some interesting specifics on the instrumentation that are still valid today.
Chandrakumar, N. and P.T. Narasimhan, Field-frequency locked X-band Overhauser effect spectrometer. Review of Scientific Instruments, 1981. 52(4): p. 533-538.
The design and construction of an Overhauser Effect Spectrometer operating at X band is described. The ESR section is a Varian V-4502 spectrometer equipped with a 9-in. electromagnet and a shim coil assembly. NMR detection is based on a broadband rf hybrid juction feeding a coil in an X-band quartz dielectric cavity. Signal processing is carried out at a constant intermediate frequency of 25.1 MHz with a Varian V -4311 fixed frequency rf unit. The mixing scheme employed to translate the NMR information to 25.1 MHz is described. Medium resolution performance (resolution _10-6 ) for the NMR is achieved under field-frequency locked conditions. The lock is based on a Super-Regenerative Oscillator (SRO) housing a control sample, and operating as a field-tracking frequency source. This SRO injects into an oscillator which excites the analytical sample resonance and also serves as a local oscillator, thereby making the locked spectrometer multinuclear in capability. Typical Overhauser effect recordings of protons and fluorines are presented.
Correction: Theory of solid effect and cross effect dynamic nuclear polarization with half-integer high-spin metal polarizing agents in rotating solids #DNPNMR
From The DNP-NMR Blog:
Correction: Theory of solid effect and cross effect dynamic nuclear polarization with half-integer high-spin metal polarizing agents in rotating solids #DNPNMR
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Corzilius, B., Correction: Theory of solid effect and cross effect dynamic nuclear polarization with half-integer high-spin metal polarizing agents in rotating solids. Phys. Chem. Chem. Phys., 2016. 18(42): p. 29643-29643.
http://dx.doi.org/10.1039/C6CP90249A
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12-17-2016 07:18 AM
Theory of solid effect and cross effect dynamic nuclear polarization with half-integer high-spin metal polarizing agents in rotating solids #DNPNMR
From The DNP-NMR Blog:
Theory of solid effect and cross effect dynamic nuclear polarization with half-integer high-spin metal polarizing agents in rotating solids #DNPNMR
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Corzilius, B., Theory of solid effect and cross effect dynamic nuclear polarization with half-integer high-spin metal polarizing agents in rotating solids. Phys. Chem. Chem. Phys., 2016. 18(39): p. 27190-27204.
http://dx.doi.org/10.1039/C6CP04621E
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11-21-2016 11:02 PM
A compact X-Band resonator for DNP-enhanced Fast-Field-Cycling NMR #DNPNMR
From The DNP-NMR Blog:
A compact X-Band resonator for DNP-enhanced Fast-Field-Cycling NMR #DNPNMR
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Neudert, O., C. Mattea, and S. Stapf, A compact X-Band resonator for DNP-enhanced Fast-Field-Cycling NMR. J Magn Reson, 2016. 271: p. 7-14.
https://www.ncbi.nlm.nih.gov/pubmed/27526396
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11-19-2016 08:35 PM
L-band Overhauser dynamic nuclear polarization
From The DNP-NMR Blog:
L-band Overhauser dynamic nuclear polarization
I must have missed that article from 2010, describing L-Band ODNP experiments. This actually looks like a very nice setup that could be used for teaching purposes.
Garcia, S., et al., L-band Overhauser dynamic nuclear polarization. J Magn Reson, 2010. 203(1): p. 138-43.
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12-03-2014 04:05 PM
The Nuclear Overhauser Effect from a Quantitative Perspective
The Nuclear Overhauser Effect from a Quantitative Perspective
Publication date: Available online 22 November 2013
Source:Progress in Nuclear Magnetic Resonance Spectroscopy</br>
Author(s): Beat Vögeli</br>
The nuclear Overhauser enhancement or effect (NOE) is the most important measure in liquid-state NMR with macromolecules. Thus, the NOE is the subject of numerous reviews and books. Here, the NOE is revisited in light of our recently introduced measurements of exact nuclear Overhauser enhancements (eNOEs), which enabled the determination of multiple-state 3D...
[NMR paper] The inter-ligand Overhauser effect: a powerful new NMR approach for mapping structura
The inter-ligand Overhauser effect: a powerful new NMR approach for mapping structural relationships of macromolecular ligands.
Related Articles The inter-ligand Overhauser effect: a powerful new NMR approach for mapping structural relationships of macromolecular ligands.
J Biomol NMR. 1999 Sep;15(1):71-6
Authors: Li D, DeRose EF, London RE
NMR experiments that transfer conformational information from the bound to the uncomplexed state via exchange have been utilized for many years. It is demonstrated here that inter-ligand NOEs ('ILOEs'),...
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11-18-2010 08:31 PM
[NMR paper] A 31P-NMR spin-lattice relaxation and 31P[1H] nuclear Overhauser effect study of soni
A 31P-NMR spin-lattice relaxation and 31P nuclear Overhauser effect study of sonicated small unilamellar phosphatidylcholine vesicles.
http://www.ncbi.nlm.nih.gov/corehtml/query/egifs/http:--linkinghub.elsevier.com-ihub-images-PubMedLink.gif Related Articles A 31P-NMR spin-lattice relaxation and 31P nuclear Overhauser effect study of sonicated small unilamellar phosphatidylcholine vesicles.
Biochim Biophys Acta. 1992 Feb 17;1104(1):137-46
Authors: Tauskela JS, Thompson M
The motional properties of the inner and outer monolayer headgroups of...
Field-frequency locked X-band Overhauser effect spectrometer #DNPNMR
Linear Mode
