Markhasin, E., et al., Efficient, balanced, transmission line RF circuits by back propagation of common impedance nodes. J. Magn. Reson., 2013. 231(0): p. 32-38.
We present a new, efficient strategy for designing fully balanced transmission line RF circuits for solid state NMR probes based on back propagation of common impedance nodes (BPCIN). In this approach, the impedance node phenomenon is the sole means of achieving mutual RF isolation and balance in all RF channels. BPCIN is illustrated using a custom double resonance 3.2 mm MAS probe operating at 500 MHz (1H) and 125 MHz (13C). When fully optimized, the probe is capable of producing high homogeneity (810°/90° ratios of 86% and 89% for 1H and 13C, respectively) and high efficiency (?B1 = 100 kHz for 1H and 13C at 70 W and 180 W of RF input, respectively; up to 360 kHz for 1H). The probe’s performance is illustrated by 2D MAS correlation spectra of microcrystals of the tripeptide N-f-MLF-OH and hydrated amyloid fibrils of the protein PI3-SH3.
[NMR paper] Efficient, balanced, transmission line RF circuits by back propagation of common impedance nodes
Efficient, balanced, transmission line RF circuits by back propagation of common impedance nodes
Available online 14 March 2013
Publication year: 2013
Source:Journal of Magnetic Resonance</br>
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We present a new, efficient strategy for designing fully balanced transmission line RF circuits for solid state NMR probes based on back propagation of a common impedance nodes (BPCIN). In this approach, the impedance node phenomenon is the sole means of achieving mutual RF isolation and balance in all RF channels. BPCIN is illustrated using a custom double resonance 3.2 mm...
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03-16-2013 02:22 AM
[Question from NMRWiki Q&A forum] NMR transmission, polarized magnetic field and rotation along x' and y' axis
NMR transmission, polarized magnetic field and rotation along x' and y' axis
I am trying to understand the workings of the NMR transmission more closely. I understand how the sinusoidally varying magnetic field created by the coil is used to tip the protons by 90deg.
I am having hard time understanding however, how using the phase shifted versions of the transmitted wave, one could achieve a 90(x') versus. 90(y') "tipping" of the protons?
Another question I have is why is circularly polarized magnetic field is required for this?
I have RF background, but I am new to the NMR...
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05-19-2012 09:22 PM
[NMRpipe Yahoo group] Re: 13C-NOESYHSQC and Back-prediction
Re: 13C-NOESYHSQC and Back-prediction
Hi All, Thanks for bringing this up, and sorry for any problems. As a work-around, I think "LP -before" will work better with root-fixing turned off using the
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04-02-2012 06:24 PM
[NMRpipe Yahoo group] Re: 13C-NOESYHSQC and Back-prediction
Re: 13C-NOESYHSQC and Back-prediction
Hello, I just wanted to comment that I have recently seen unusual artefacts being generated when using back prediction in a similar fashion. I have not yet had
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04-02-2012 05:15 AM
[Ryan's blog] Back to Reality #1- LC/MS vs. NMR
Source: Ryan's blog
Back to Reality #1- LC/MS vs. NMR
Reality #1: LC/MS has become the primary analytical check for the medicinal chemist. I Love NMR, but it's the reality So how did we get here? Clearly there a lot of reasons, but one of my hypotheses is based on...
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06-10-2011 01:41 AM
[NMR paper] Prevention of aggregation after refolding by balanced stabilization-destabilization:
Prevention of aggregation after refolding by balanced stabilization-destabilization: production of the Arabidopsis thaliana protein APG8a (At4g21980) for NMR structure determination.
Related Articles Prevention of aggregation after refolding by balanced stabilization-destabilization: production of the Arabidopsis thaliana protein APG8a (At4g21980) for NMR structure determination.
Protein Expr Purif. 2004 Apr;34(2):280-3
Authors: Chae YK, Im H, Zhao Q, Doelling JH, Vierstra RD, Markley JL
The gene coding for APG8a (At4g21980), a protein from...
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11-24-2010 09:51 PM
[NMR paper] Analysis of error propagation from NMR-derived internuclear distances into molecular
Analysis of error propagation from NMR-derived internuclear distances into molecular structure of cyclo-pro-gly.
Related Articles Analysis of error propagation from NMR-derived internuclear distances into molecular structure of cyclo-pro-gly.
J Magn Reson. 1998 Dec;135(2):454-65
Authors: Dzakula Z, Jurani? , DeRider ML, Westler WM, Macura S, Markley JL
Analytical expressions have been derived that translate uncertainties in distance constraints (obtained from NMR investigations) into uncertainties in atom positions in the maximum likelihood...
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11-17-2010 11:15 PM
[NMR analysis blog] Back in the blogosphere
Back in the blogosphere
After a 3 month-long hiatus, I'm back in the blogosphere. I’ve been travelling and working very hard on several exciting projects, but my entries have consequently suffered.
Although my workload has not decreased, I am not planning to travel for the next few weeks. Hopefully I will manage to blog on a more regular basis from now on, especially now that there are many things we have been working on lately that I hope will be of interest to the NMR community.
For now, I’d just like to point out a very interesting blog entry written by my friend Stan on his...