NMR paper Acidity Strength of Solid Catalysts Probed by Hyperpolarized Natural Abundance 17O NMR Spectroscopy

		BioNMR > Educational resources > Journal club
[NMR paper] Acidity Strength of Solid Catalysts Probed by Hyperpolarized Natural Abundance 17O NMR Spectroscopy

Webservers

NMR processing:

MDD

NMR assignment:

Backbone:

Side-chains:

NOEs:

Structure from NMR restraints:

Ab initio:

Fragment-based:

Rosetta-NMR (Robetta)

Template-based:

GeNMR

I-TASSER

Refinement:

Amber

Structure from chemical shifts:

Fragment-based:

Homology-based:

Torsion angles from chemical shifts:

Preditor

TALOS

Promega- Proline

Secondary structure from chemical shifts:

CSI (via RCI server)

TALOS

MICS caps, β-turns

d2D

PECAN

Flexibility from chemical shifts:

RCI

Interactions from chemical shifts:

HADDOCK

Chemical shifts re-referencing:

NMR model quality:

NOEs, other restraints:

Chemical shifts:

RDCs:

Pseudocontact shifts:

Protein geomtery:

SAVES2 or SAVES4

Quality Control Check

NMR spectrum prediction:

FANDAS

MestReS

V-NMR

Flexibility from structure:

Backbone S2

Methyl S2

B-factor

Molecular dynamics:

Gromacs

Amber

Antechamber

Chemical shifts prediction:

From structure:

Shiftx2

Sparta+

Camshift

CH3shift- Methyl

ArShift- Aromatic

ShiftS

Proshift

PPM

CheShift-2- Cα

From sequence:

Shifty

Camcoil

Poulsen_rc_CS

Disordered proteins:

MAXOCC

Format conversion & validation:

CCPN

From NMR-STAR 3.1

Validate NMR-STAR 3.1

NMR sample preparation:

Protein disorder:

DisMeta

Protein solubility:

Isotope labeling:

Solid-state NMR:

Thread Tools

Search this Thread

Rate Thread

Display Modes

07-11-2017, 09:20 AM

nmrlearner

Senior Member

Join Date: Jan 2005

Posts: 23,732

Points: 193,617, Level: 100

Level up: 0%, 0 Points needed

Activity: 50.7%

Last Achievements

Award-Showcase

NMR Credits: 0

NMR Points: 193,617

Downloads: 0

Uploads: 0

Acidity Strength of Solid Catalysts Probed by Hyperpolarized Natural Abundance 17O NMR Spectroscopy

Acidity Strength of Solid Catalysts Probed by Hyperpolarized Natural Abundance 17O NMR Spectroscopy

Observation of Brønsted acid sites: By enhancing the solid-state NMR signals of 17O at natural abundance with dynamic nuclear polarization (DNP), Pruski et al. were able to measure oxygen–proton distances accurately with sub-picometer precision. The results give insight into the Brønsted acidity of a range of solid acid catalysts.

More...

Did you find this post helpful?

Similar Threads
Thread	Thread Starter	Forum	Replies	Last Post
[NMR paper] Natural Abundance 17O DNP NMR Provides Precise O-H Distances and Insights into the Brønsted Acidity of Heterogeneous Catalysts Natural Abundance 17O DNP NMR Provides Precise O-H Distances and Insights into the Brønsted Acidity of Heterogeneous Catalysts Brønsted acidic sites on catalyst surfaces are observed by 17O dynamic nuclear polarization-enhanced NMR spectroscopy, which hyperpolarizes nuclei by microwave-induced saturation of electrons. In their Communication (DOI: 10.1002/anie.201704032), M. Pruski et al. report the measurement of O-H distances with sub-picometer precision. The length of the O-H bond is directly related to the Brønsted acidity of the sites and is also a reporter of the formation of...	nmrlearner	Journal club	0	06-12-2017 01:48 PM
[NMR paper] Hydrogen bond strength in membrane proteins probed by time-resolved (1)H-detected solid-state NMR and MD simulations. Hydrogen bond strength in membrane proteins probed by time-resolved (1)H-detected solid-state NMR and MD simulations. Related Articles Hydrogen bond strength in membrane proteins probed by time-resolved (1)H-detected solid-state NMR and MD simulations. Solid State Nucl Magn Reson. 2017 Mar 18;: Authors: Medeiros-Silva J, Jekhmane S, Baldus M, Weingarth M Abstract (1)H-detected solid-state NMR in combination with (1)H/(2)D exchange steps allows for the direct identification of very strong hydrogen bonds in membrane proteins....	nmrlearner	Journal club	0	03-28-2017 03:06 PM
Hyperpolarized NMR of plant and cancer cell extracts at natural abundance From The DNP-NMR Blog: Hyperpolarized NMR of plant and cancer cell extracts at natural abundance Dumez, J.N., et al., Hyperpolarized NMR of plant and cancer cell extracts at natural abundance. Analyst, 2015. 140(17): p. 5860-3. http://www.ncbi.nlm.nih.gov/pubmed/26215673	nmrlearner	News from NMR blogs	0	12-03-2015 02:03 AM
Quantitative Structural Constraints for Organic Powders at Natural Isotopic Abundance Using Dynamic Nuclear Polarization Solid-State NMR Spectroscopy From The DNP-NMR Blog: Quantitative Structural Constraints for Organic Powders at Natural Isotopic Abundance Using Dynamic Nuclear Polarization Solid-State NMR Spectroscopy Mollica, G., et al., Quantitative Structural Constraints for Organic Powders at Natural Isotopic Abundance Using Dynamic Nuclear Polarization Solid-State NMR Spectroscopy. Angewandte Chemie, 2015. 127(20): p. 6126-6129. http://dx.doi.org/10.1002/ange.201501172	nmrlearner	News from NMR blogs	0	10-03-2015 09:52 AM
Natural Abundance 17O DNP Two-Dimensional and Surface-Enhanced NMR Spectroscopy Natural Abundance 17O DNP Two-Dimensional and Surface-Enhanced NMR Spectroscopy Fre?de?ric A. Perras, Takeshi Kobayashi and Marek Pruski http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/jacsat/0/jacsat.ahead-of-print/jacs.5b03905/20150629/images/medium/ja-2015-03905b_0003.gif Journal of the American Chemical Society DOI: 10.1021/jacs.5b03905 http://feeds.feedburner.com/~ff/acs/jacsat?d=yIl2AUoC8zA http://feeds.feedburner.com/~r/acs/jacsat/~4/2XY9E0YdGEg	nmrlearner	Journal club	0	06-29-2015 07:21 PM
Matrix-free dynamic nuclear polarization enables solid-state NMR (13)C-(13)C correlation spectroscopy of proteins at natural isotopic abundance From The DNP-NMR Blog: Matrix-free dynamic nuclear polarization enables solid-state NMR (13)C-(13)C correlation spectroscopy of proteins at natural isotopic abundance Takahashi, H., S. Hediger, and G. De Paepe, Matrix-free dynamic nuclear polarization enables solid-state NMR (13)C-(13)C correlation spectroscopy of proteins at natural isotopic abundance. Chem Commun (Camb), 2013. 49(82): p. 9479-81. http://www.ncbi.nlm.nih.gov/pubmed/24013616	nmrlearner	News from NMR blogs	0	11-21-2013 01:14 AM
[NMR paper] Matrix-free dynamic nuclear polarization enables solid-state NMR (13)C-(13)C correlation spectroscopy of proteins at natural isotopic abundance. Matrix-free dynamic nuclear polarization enables solid-state NMR (13)C-(13)C correlation spectroscopy of proteins at natural isotopic abundance. Matrix-free dynamic nuclear polarization enables solid-state NMR (13)C-(13)C correlation spectroscopy of proteins at natural isotopic abundance. Chem Commun (Camb). 2013 Sep 6; Authors: Takahashi H, Hediger S, De Paëpe G Abstract We introduce a general approach for dynamic nuclear polarization (DNP) enhanced solid-state NMR that overcomes the current problems in DNP experiments caused by the use...	nmrlearner	Journal club	0	09-10-2013 08:44 PM
Identifying Guanosine Self Assembly at Natural Isotopic Abundance by High-Resolution 1H and 13C Solid-State NMR Spectroscopy Identifying Guanosine Self Assembly at Natural Isotopic Abundance by High-Resolution 1H and 13C Solid-State NMR Spectroscopy Amy L. Webber, Stefano Masiero, Silvia Pieraccini, Jonathan C. Burley, Andrew S. Tatton, Dinu Iuga, Tran N. Pham, Gian Piero Spada and Steven P. Brown http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/jacsat/0/jacsat.ahead-of-print/ja206516u/aop/images/medium/ja-2011-06516u_0007.gif Journal of the American Chemical Society DOI: 10.1021/ja206516u http://feeds.feedburner.com/~ff/acs/jacsat?d=yIl2AUoC8zA...	nmrlearner	Journal club	0	11-18-2011 04:35 AM

« Previous Thread | Next Thread »

Posting Rules
You may not post new threads You may not post replies You may not post attachments You may not edit your posts BB code is On Smilies are On [IMG] code is On HTML code is On Trackbacks are Off Pingbacks are Off Refbacks are Off