When it comes to plutonium, things are complicated. The radioactive element comes with a lot of technical and regulatory baggage. Now, a team at the Pacific Northwest National Laboratory and Washington State University have used fluorine-19 nuclear magnetic resonance (NMR) spectroscopy to take a close look at the element's inner electronic secrets when it finds itself in the superficially simple compound plutonium tetrafluoride.
Dynamic nuclear polarization with photoexcited triplet electrons in a glassy matrix
From The DNP-NMR Blog:
Dynamic nuclear polarization with photoexcited triplet electrons in a glassy matrix
Tateishi, K., et al., Dynamic nuclear polarization with photoexcited triplet electrons in a glassy matrix. Angew Chem Int Ed Engl, 2013. 52(50): p. 13307-10.
http://www.ncbi.nlm.nih.gov/pubmed/24249595
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04-25-2014 10:26 PM
[Question from NMRWiki Q&A forum] Why do unpaired electrons make NMR measurements difficult?
Why do unpaired electrons make NMR measurements difficult?
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